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Oxygen Radical Dyanmics


The study of reactions at the gas-liquid interface presents a challenge due to the complex nature of liquid surfaces. We have developed an experimental method in which we detect the gas-phase products spectroscopically after reaction/collision with a liquid surface, deriving internal and translational energy distributions. This allows us to interrogate the fundamental steps involved in gas-liquid interfacial processes.


Reactive scattering of O(3P) + hydrocarbons

Gaseous O(3P) atoms are created by laser photolysis of NO2 at a short distance above the liquid surface. On impact with the surface, some of the O(3P) abstracts a hydrogen atom, generating OH radicals that escape from the surface. These are probed in the gas phase by laser induced fluorescence (LIF).

O(3P) scattering from hydrocarbons simulation

We have successfully employed this method to study interfacial reactions with a variety of hydrocarbons and self-assembled monolayers. Our most recent work focused on introducing unsaturated sites in the hydrocarbon backbone to study the effect on the interfacial dynamics. The partially unsaturated hydrocarbon squalene was compared against its saturated analogue, squalane. The scattered products show different energy distributions due to inherently different H-abstraction dynamics, but there is also partial thermal accommodation of OH at the liquid surface, a feature of most gas-liquid reactions. The OH yields from both liquids are dramatically different, indicating the presence of unsaturated groups at the squalene surface. The O(3P) atoms are likely to be lost by competitive addition to the double bonds.

MD simulation of squalene surface

MD snapshot of a squalene surface (top view). Red atoms indicate unsaturated sites.


Inelastic OH scattering

OH radicals present in the troposphere are the predominant daytime atmospheric oxidants. The reaction of OH with organic molecules in aerosols has an impact on our climate; therefore it is important to gain an understanding of its mechanism. In our group we study these processes from a fundamental point of view, characterizing the collision dynamics of OH radicals with different hydrocarbon liquids. OH is generated by photolysis of a suitable precursor, and radicals that scatter from the surface are detected by LIF. We investigate scattering of OH molecules from reactive and inert liquid surfaces. This gives us the opportunity to estimate the fraction of OH radicals which do not escape from liquid surfaces. Potentially reactive hydrocarbons with abstractable H atoms (squalane, squalene and oleic acid) produce less scattered OH than the inert liquid PFPE. A comparison between squalane and squalene provides evidence that the thermalised products are lost on addition to the unsaturated sites (see figure below). Squalane is the most efficient at energy transfer to the surface, whereas PFPE gives a more elastic surface resulting in scattered products with higher energy. Using a different OH precursor (allyl alcohol or HONO) produces incoming OH radicals with different energy distributions, providing complementary information on the scattering dynamics. Rotationally cold OH radicals from HONO are suitable for observing translational-to-rotational energy transfer in direct collisions. In contrast, the broader OH rotational distributions obtained from allyl alcohol allow us to distinguish between directly scattered and thermalised products.

OH appearance profiles

OH appearance profiles from squalane (red open squares) and squalene (blue filled circles), acquired in the Q1(1) transition of the A-X (1,0) band by varying the delay between photolysis and probe laser pulses. Composite profiles (blue open circles) are the sum of the squalene profile and an adjustable weighted contribution from a Monte-Carlo simulation of a thermal component (solid red line).


  1. Site and bond-specific dynamics of reactions at the gas-liquid interface

    Maria A. Tesa-Serrate, Kerry L. King, Grant Paterson, Matthew L. Costen and Kenneth G. McKendrick

    Physical Chemistry Chemical Physics (2014) 16, 173

    doi: 10.1039/c3cp54107j

  2. Inelastic scattering of OH radicals from organic liquids: isolating the thermal desorption channel

    Kerry L. King, Grant Paterson, Giovanni Rossi, Maria Iljina, Robin E. Westacott, Matthew L. Costen and Kenneth G. McKendrick

    Physical Chemistry Chemical Physics (2013), 15, 12852

    doi: 10.1039/c3cp51708j

  3. Collision Dynamics and reactive uptake of OH radicals at liquid surfaces of atmospheric interest

    Carla Waring, Kerry L. King, Paul A. J. Bagot, Matthew L. Costen and Kenneth G. McKendrick

    Physical Chemistry Chemical Physics (2011), 13, 8457

    doi: 10.1039/c0cp02734k

    See our perspectives video here

  4. Dynamics of the Gas-Liquid Interfacial Reaction of O(1D) with a Liquid Hydrocarbon

    Kenneth G. McKendrick, Carla Waring, Kerry L. King and Matthew L. Costen

    Journal of Physical Chemistry A (2011), 115, 7210

    doi: doi



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